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Application of high-speed counter-current chromatography coupled with high performance liquid chromatography

Shengguo DENG, Zeyuan DENG, Yawei FAN, Jing LI, Rong LIU, Dongmei XIONG,

《化学科学与工程前沿（英文）》 2009年 第3卷 第4期   页码 375-382 doi: 10.1007/s11705-009-0247-9

摘要： Quercetin-3--sambubioside Quercetin-3--β-D-xylopyranosyl (1→2)-β-D-glucopyranoside was separated and purified by semi-preparative high-speed counter-current chromatography (HSCCC) with a two-phase-solvent system composed of ethyl acetate-n-butanol–water (4∶1∶5, v/v) from the leaves of (Lotus). A total of 5.0mg of the targeted compound with a purity of 98.6% as determined by high performance liquid chromatography (HPLC) was obtained from 100m g of the crude extract cleaned up by AB-8 macroporous resin in a one-step separation. Quercetin-3--sambubioside was a novel flavonoid glycoside from the leaves of , and its chemical structure was identified by means of ESI-MS, 1D NMR and 2D NMR.

关键词： two-phase-solvent     flavonoid glycoside     high-speed counter-current     macroporous     counter-current chromatography    

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Effect of counter current gas phase on liquid film

Shujuan LUO, Huaizhi LI, Weiyang FEI, Yundong WANG

《化学科学与工程前沿（英文）》 2009年 第3卷 第2期   页码 135-137 doi: 10.1007/s11705-009-0129-1

摘要： Liquid film flow is very important in many industrial applications. However, there are few reports about its characteristics on structured packings. Therefore, in this paper, liquid film phenomena were investigated experimentally to exploit new approaches for intensifying the performance of the structured packings. All experiments were performed at room temperature. Water and air were the working fluids. The effect of counter current gas phase on the liquid film was taken into consideration. A high speed camera, a non-intrusive measurement technique, was used. It is shown that both liquid and gas phases have strong effects on film characteristics. In the present work, liquid film width increased by 57% because of increasing liquid flow rate, while it decreased by 25% resulting from the counter current gas phase.

关键词： counter current     liquid film     two phases     structured packings    

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Development of a cloud condensation nuclei (CCN) counter using a laser and charge-coupled device (CCD

Mikyung PARK, Jinkwan OH, Kihong PARK

《环境科学与工程前沿（英文）》 2011年 第5卷 第3期   页码 313-319 doi: 10.1007/s11783-011-0346-y

摘要： A continuous flow streamwise thermal gradient cloud condensation nuclei (CCN) counter with an aerosol focusing and a laser-charge-coupled device (CCD) camera detector system was developed here. The counting performance of the laser-CCD camera detector system was evaluated by comparing its measured number concentrations with those measured with a condensation particle counter (CPC) using polystyrene latex (PSL) and NaCl particles of varying sizes. The CCD camera parameters (e.g. brightness, gain, gamma, and exposure time) were optimized to detect moving particles in the sensing volume and to provide the best image to count them. The CCN counter worked well in the particle number concentration range of 0.6–8000 #·cm and the minimum detectable size was found to be 0.5 μm. The supersaturation in the CCN counter with varying temperature difference was determined by using size-selected sodium chloride particles based on K?hler equation. The developed CCN counter was applied to investigate CCN activity of atmospheric ultrafine particles at 0.5% supersaturation. Data showed that CCN activity increased with increasing particle size and that the higher CCN activation for ultrafine particles occurred in the afternoon, suggesting the significant existence of hygroscopic or soluble species in photochemically-produced ultrafine particles.

关键词： aerosol     cloud condensation nuclei (CCN) counter     ultrafine particle    

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Thermodynamic performance experiment and cooling number calculation of a counter-flow spray humidifier

WANG Yuzhang, LI Yixing, WENG Shilie, WANG Yonghong

《能源前沿（英文）》 2008年 第2卷 第1期   页码 43-47 doi: 10.1007/s11708-008-0005-6

摘要： An experimental investigation of the thermodynamic performance of a counter-flow spray humidifier was conducted on the basis of theoretical analysis of the heat and mass transfer mechanism inside the humidifier. Critical parameters such as the temperature and relative humidity of air and the temperature of water at the inlet and outlet were measured. The influence of every measured parameter on the thermal performance of the humidifier was obtained under different experimental conditions. The cooling number, whose variation was also obtained, was calculated according to the measured data. The experimental results show that both the temperature and the temperature increment of outlet humid air and the temperature of outlet water increase with an increase of the water-gas ratio, whereas the cooling number decreases. Under all experimental conditions, the outlet humid air reaches or is close to the saturation level. The lower cooling number is favorable for the system, but it has an optimal value for a certain humidifier.

关键词： temperature increment     counter-flow     experimental investigation     temperature     water-gas    

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Finite element modeling of counter-roller spinning for large-sized aluminum alloy cylindrical parts

Dawei ZHANG, Fan LI, Shuaipeng LI, Shengdun ZHAO

《机械工程前沿（英文）》 2019年 第14卷 第3期   页码 351-357 doi: 10.1007/s11465-019-0528-z

摘要： Counter-roller spinning (CRS), where the mandrel is replaced by rollers, is an effective means of manufacturing large-sized, thin-walled, cylindrical parts with more than 2500 mm diameter. CRS is very complex because of multi-axis rotation, multi-local loading along the circumference, and radial-axial compound deformation. Analytical or experimental methods cannot fully understand CRS. Meanwhile, numerical simulation is an adequate approach to investigate CRS with comprehensive understanding and a low cost. Thus, a finite element (FE) model of CRS was developed with the FORGE code via meshing technology, material modeling, determining the friction condition, and so on. The local fine mesh moving with the roller is one of highlights of the model. The developed 3D-FE model was validated through a CRS experiment by using a tubular blank with a 720 mm outer diameter. The developed 3D-FE model of CRS can provide a basis for parameter optimization, process control, die design, and so on. The data on force and energy predicted by the 3D-FE model can offer reasonable suggestions for determining the main mechanical parameters of CRS machines and selecting the motors. With the predicted data, an all-electric servo-drive system/machine with distributed power was designed in this work for CRS with four pairs of rollers to manufacture a large-sized, thin-walled, cylindrical part with 6000 mm diameter.

关键词： large-sized cylindrical part     counter-roller spinning     aluminum alloy     finite element method     distributed power    

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The Development Situation, Future and Counter Measures of Remanufacturing Industry in China

Wen-qiang Liu,Jun-yuan Mo,Cheng-kui Gu

《工程管理前沿（英文）》 2016年 第3卷 第2期   页码 123-131 doi: 10.15302/J-FEM-2016021

摘要： Currently, resource supply and demand contradiction, and over-loaded environment capacity have become a bottleneck for sustainable economic development in China. Electro-mechanical products are approaching a peak of obsolescence, and massive abandoned electro-mechanical products are causing severe environmental pollution, huge waste of resources and potential safety hazard. Remanufacturing is repairing or modifying worn mechanical products using high-tech method, which buffers the contradiction between wasting and shortage of resources, and brings industry towards a comprehensive utilization of resource and environmental protection. As a new strategic industry, remanufacturing, which is highly coherent with the development strategy of the circular economy, is still in its infancy in China. This paper analyzes the developmental trends and problems of the remanufacturing industry in China, and proposes promoting measures based on the engineering practices of remanufacturing.

关键词： remanufacturing     industry     measures     development    

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isopropylacrylamide with 3-(methacryloxy)propyl trimethoxysilane on ultrafine silica and its application in chromatography

ZHANG Liping, ZHU Yi, NI Caihua

《化学科学与工程前沿（英文）》 2008年 第2卷 第3期   页码 242-247 doi: 10.1007/s11705-008-0043-y

摘要： Thermosensitive core-shell particles were synthesized through graft copolymerization of -isopropylacrylamide with [ 3-(methacryloxy) propyl]trimethoxysilane (MPT) coupled on the surface of ultrafine silica beads. The copolymerization was carried out using polyvinyl alcohol as a surfactant, water and cyclohexanol as mixed solvent, and 2,2′-azobis(isobutyronitrile) as an initiator. The effect of surfactant concentration and the composition of the mixed solvent on the graft rate were investigated. The structure of modified silica was confirmed by infrared spectra. Differential scanning calorimetry (DSC) has revealed the thermosensitivity of the particles. The thermosensitive particles were used as packing materials of high performance liquid chromatography (HPLC) columns for separating naphthalene derivatives. Satisfactory separation was obtained by controlling the temperature of the column. In contrast, the packing material of silica-MPT has no such separation efficiency due to the lack of thermosensitivity. The effect of the composition of the mobile phase on the separating efficiency was also investigated. The temperature-controlled separation was effective only when the water content was higher than 90% (v/v) in the water-methanol mobile phase. The mechanism for the temperature-controlled separation is attributed to a polarity change of poly(-isopropylacrylamide) which undergoes volume phase transition on the silica surface as the temperature increases.

关键词： undergoes     water-methanol     surfactant concentration     copolymerization     chromatography    

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Fast determination of tobramycin by reversed-phase ion-pair high performance liquid chromatography with

Liang ZHU, Jingkang WANG

《化学科学与工程前沿（英文）》 2013年 第7卷 第3期   页码 322-328 doi: 10.1007/s11705-013-1348-z

摘要： A simple and direct method without a derivation step for routine analysis of tobramycin has been developed. This method used reversed-phase ion-pair high performance liquid chromatography (HPLC) with a refractive index (RI) detector and a C18 column which is stable at pH above 1.00. The presence of 4.50 mg·mL trifluoroacetic acid (TFA) in the mobile phase improved the protonation of tobramycin and the formation of ion-pairs, and thus reduced its hydrophility. This unique separation–detection combination showed good linearity with correlation coefficients 0.9996 in the concentration range of 0.25–2.50 mg·mL . The quantitation limit and detection limit were determined to be 0.23 mg·mL and 0.071 mg·mL , respectively. Tobramycin was recovered in 98.00%, 98.84% and 99.64% for tobramycin solutions at concentrations of 2.25 mg·mL , 1.50 mg·mL and 0.75 mg·mL , respectively. The relative standard deviations for six spiked samples ranged from 0.20% to 2.40%, indicating a good reproducibility of this method.

关键词： tobramycin     aminoglycoside     refractive index detector     high-performance liquid chromatography     ion-pairing    

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Simultaneous analysis of five taste and odor compounds in surface water using solid-phase extraction and gas chromatography-mass

Wenfeng SUN, Ruibao JIA, Baoyu GAO

《环境科学与工程前沿（英文）》 2012年 第6卷 第1期   页码 66-74 doi: 10.1007/s11783-010-0257-3

摘要： In this paper, a method using solid-phase extraction (SPE) and gas chromatography-mass spectrometry (GC-MS) was developed to simultaneously analyze five taste and odor compounds in surface water, i.e., 2-methylisoborneol (2-MIB), 2,4,6-trichloroanisole (TCA), 2-isopropyl-3-methoxy pyrazine (IPMP), 2-isobutyl-3-methoxy pyrazine (IBMP), and -1,10-dimethyl- -9-decalol (geosmin, GSM). The mass spectrometry was operated in selective ion monitoring (SIM) mode. Three kinds of SPE columns and three eluting solvents were compared, the C18 column was chosen as optimum SPE column, and methanol was chosen as the optimum eluting solvent. It was found that the method showed good linearity in the range of 1–200 ng·L and gave detection limits of 0.5–1.5 ng·L for individual compounds. Good recoveries (93.5%–108%) and relative standard deviations (1.58%–7.31%) were also obtained. Additionally, concentrations of these taste and odor compounds in Jinan’s surface and drinking water were analyzed by applying this method, and the results showed that GSM and 2-MIB were the dominant taste and odor compounds in Jinan’s raw water.

关键词： solid-phase extraction (SPE)     gas chromatography-mass spectrometry (GC-MS)     taste and odor compounds     surface water     micropollutant    

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用于图像融合基于混合全加器和计数器的高效华莱士树型乘法器 Research Articles

Ayoub SADEGHI, Nabiollah SHIRI, Mahmood RAFIEE, Mahsa TAHGHIGH

《信息与电子工程前沿（英文）》 2022年 第23卷 第6期   页码 950-965 doi: 10.1631/FITEE.2100432

摘要：

提出一种新的基于计数器的华莱士树（CBW）8×8乘法器。乘法器的计数器使用基于传输门技术的新型混合全加器单元。所提全加器、基于传输门的与门和混合半加器生成M:3（4≤M≤7）数字计数器，能够节省至少50%的面积。通过90 nm技术仿真证明所提全加器和数字计数器在不同条件下均优于当前最先进设计。通过使用所提单元，CBW乘法器表现出高驱动、低功耗和高速性能。CBW乘法器在焊盘中的芯片面积为0.0147 mm2。后布局提取证明了实验的准确性。同时提出一种图像融合机制，其中MATLAB和HSPICE之间的直接接口用于在图像处理应用中评估所提CBW乘法器。峰值信噪比和结构相似性指数度量被用作图像质量参数，结果证实所提CBW乘法器可以替代文献中的设计。

关键词： 全加器；传输门；计数器；乘法器；三维布局；图像融合    

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Simultaneous quantification of several classes of antibiotics in water, sediments, and fish muscles by liquid chromatography–tandem

WEI Yimei,ZHANG Yuan,XU Jian,GUO Changsheng,LI Lei,FAN Wenhong

《环境科学与工程前沿（英文）》 2014年 第8卷 第3期   页码 357-371 doi: 10.1007/s11783-013-0580-6

摘要： Precise and sensitive methods for the simultaneous determination of different classes of antibiotics, including sulphonamides, fluoroquinolones, macrolides, tetracyclines, and trimethoprim in surface water, sediments, and fish muscles were developed. In water samples, drugs were extracted with solid-phase extraction (SPE) by passing 1000 mL of water through hydrophilic lipophilic balanced (HLB) SPE cartridges. Sediment samples were solvent-extracted, followed by tandem SPE (strong anion exchange (SAX) + HLB) clean-ups. Fish muscles were extracted by a mixture of acetonitrile and citric buffer (80:20, v/v) solution, and cleaned by SPE. Liquid chromatography–tandem mass spectrometry (LC-MS/MS) with multiple reaction monitoring (MRM) detection was employed to quantify all compounds. The recoveries for the antibiotics in the spiked water, sediment, and fish samples were 60.2%–95.8%, 48.1%–105.3%, and 59.8%–103.4%, respectively. The methods were applied to samples taken from Dianchi Lake, China. It showed that concentrations of the detected antibiotics ranged from limits of quantification (LOQ) to 713.6 ng·L (ofloxacin) in surface water and from less than LOQ to 344.8 μg·kg (sulphamethoxazole) in sediments. The number of detected antibiotics and the overall antibiotic concentrations were higher in the urban area than the rural area, indicating the probable role of livestock and human activities as important sources of antibiotic contamination. In fish muscles, the concentration of norfloxacin was the highest (up to 38.5 μg·kg ), but tetracyclines and macrolides were relatively low. Results showed that the methods were rapid and sensitive, and capable of determining several classes of antibiotics from each of the water, sediment, and fish matrices in a single run.

关键词： antibiotics     liquid chromatography–tandem mass spectrometry (LC-MS/MS)     water     sediment     fish muscle    

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Numerical analysis of 3-D unsteady flow in a vaneless counter-rotating turbine

ZHAO Qingjun, WANG Huishe, ZHAO Xiaolu, XU Jianzhong

《能源前沿（英文）》 2007年 第1卷 第3期   页码 352-358 doi: 10.1007/s11708-007-0053-3

摘要： To reveal the unsteady flow characteristics of a vaneless counter-rotating turbine (VCRT), a three-dimensional, viscous, unsteady computational fluid dynamics (CFD) analysis was performed. The results show that unsteady simulation is superior to steady simulation because more flow characteristics can be obtained. The unsteady effects in upstream airfoil rows are weaker than those in downstream airfoil rows in the VCRT. The static pressure distribution along the span in the pressure surface of a high pressure turbine stator is more uniform than that in the suction surface. The static pressure distributions along the span in the pressure surfaces and the suction surfaces of a high pressure turbine rotor and a low pressure turbine rotor are all uneven. The numerical results also indicate that the load of a high pressure turbine rotor will increase with the increase of the span. The deviation is very big between the direction of air flow at the outlet of a high pressure turbine rotor and the axial direction. A similar result can also be obtained in the outlet of a low pressure turbine rotor. This means that the specific work of a high pressure turbine rotor and a low pressure turbine rotor is big enough to reach the design objectives.

关键词： unsteady flow     three-dimensional     pressure distribution     similar result     unsteady simulation    

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Effect of ligand chain length on hydrophobic charge induction chromatography revealed by molecular dynamics

Lin ZHANG, Yan SUN

《化学科学与工程前沿（英文）》 2013年 第7卷 第4期   页码 456-463 doi: 10.1007/s11705-013-1357-y

摘要： Hydrophobic charge induction chromatography (HCIC) is a mixed-mode chromatography which is advantageous for high adsorption capacity and facile elution. The effect of the ligand chain length on protein behavior in HCIC was studied. A coarse-grain adsorbent pore model established in an earlier work was modified to construct adsorbents with different chain lengths, including one with shorter ligands (CL2) and one with longer ligands (CL4). The adsorption, desorption, and conformational transition of the proteins with CL2 and CL4 were examined using molecular dynamics simulations. The ligand chain length has a significant effect on both the probability and the irreversibility of the adsorption/desorption. Longer ligands reduced the energy barrier of adsorption, leading to stronger and more irreversible adsorption, as well as a little more unfolding of the protein. The simulation results elucidated the effect of the ligand chain length, which is beneficial for the rational design of adsorbents and parameter optimization for high-performance HCIC.

关键词： adsorption     desorption     irreversibility     protein conformational transition     molecular dynamics simulation    

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analysis of off-flavor/odor compounds in water using liquid-liquid microextraction coupled with gas chromatography—positive

Jian LU,Paul S. WILLS,P. CHRIS WILSON

《环境科学与工程前沿（英文）》 2016年 第10卷 第3期   页码 477-481 doi: 10.1007/s11783-015-0820-z

摘要： A rapid, inexpensive and laboratory friendly method was developed for analysis of off-flavor/odor compounds in fresh and salt water using gas chromatography with chemical ionization-tandem mass spectrometry. Off-flavor/odor compounds included geosmin, 2-methylisoborneol (MIB), 2-isobutyl-3-methyoxypyrazine (IBMP), and 2-isopropyl-3-methoxypyrazine (IPMP). Using this method, a single sample can be extracted within minutes using only 1 mL of organic solvent. The ion transitions for IPMP, IBMP, MIB, and geosmin were 153>121, 167>125, 152>95, and 165>109, respectively. The linearity of this method for analyzing MIB ranged from 4 to 200 ng·L , and from 0.8 to 200 ng·L for the other analytes. Method recoveries ranged from 97% to 111% and percent relative standard deviations ranged from 3% to 9%, indicating that the method is accurate, precise, and reliable.

关键词： off-flavor/odor compounds     liquid-liquid microextraction     gas chromatography-tandem mass spectrometry    

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基于量子点元胞自动机的低能耗、高速度和高效面积时序电路：T型锁存器和计数器研究 Research Article

Mohammad GHOLAMI1,Zaman AMIRZADEH2

《信息与电子工程前沿（英文）》 2023年 第24卷 第3期   页码 457-469 doi: 10.1631/FITEE.2200361

摘要： 量子点元胞自动机（QCA）是一种用于实现纳米数字电路的新型纳米技术。这种纳米技术在速度、面积和功耗方面都优于互补金属氧化物半导体（CMOS）技术，并且可以显著改善各种逻辑电路设计。本文提出一种在QCA技术中实现T型锁存器的新方法，该方法利用了QCA在时序和时钟相位上的固有特征，因此，所提单元结构与现有方法相比占用面积更少，功耗更低。与之前的最佳设计相比，该T型锁存器的占用面积减少6.45%，功耗降低44.49%。此外，本文首次设计了基于复位的T型锁存器和具有置位和复位功能的T型锁存器。基于所提T型锁存器，开发了一种新型3位计数器，与之前的最佳设计相比减少2.14%的单元数。在3位计数器的基础上，设计了4位计数器，与之前的设计相比，减少0.51%的单元数和4.16%的截面积。此外还引入两个选择性计数器，分别从0到5和从2到5进行计数。在相干矢量引擎模式下，使用QCADesigner和QCAPro软件进行模拟，并将所提电路与相关设计在延迟、单元数、面积和漏电功率方面进行了比较。

关键词： 量子点元胞自动机（QCA）；量子点；T型锁存器；T型触发器；计数器；选择性计数器；QCADesigner软件；QCAPro软件    

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标题 作者 时间 类型 操作

Application of high-speed counter-current chromatography coupled with high performance liquid chromatography

Shengguo DENG, Zeyuan DENG, Yawei FAN, Jing LI, Rong LIU, Dongmei XIONG,

期刊论文

Effect of counter current gas phase on liquid film

Shujuan LUO, Huaizhi LI, Weiyang FEI, Yundong WANG

期刊论文

Development of a cloud condensation nuclei (CCN) counter using a laser and charge-coupled device (CCD

Mikyung PARK, Jinkwan OH, Kihong PARK

期刊论文

Thermodynamic performance experiment and cooling number calculation of a counter-flow spray humidifier

WANG Yuzhang, LI Yixing, WENG Shilie, WANG Yonghong

期刊论文

Finite element modeling of counter-roller spinning for large-sized aluminum alloy cylindrical parts

Dawei ZHANG, Fan LI, Shuaipeng LI, Shengdun ZHAO

期刊论文

The Development Situation, Future and Counter Measures of Remanufacturing Industry in China

Wen-qiang Liu,Jun-yuan Mo,Cheng-kui Gu

期刊论文

isopropylacrylamide with 3-(methacryloxy)propyl trimethoxysilane on ultrafine silica and its application in chromatography

ZHANG Liping, ZHU Yi, NI Caihua

期刊论文

Fast determination of tobramycin by reversed-phase ion-pair high performance liquid chromatography with

Liang ZHU, Jingkang WANG

期刊论文

Simultaneous analysis of five taste and odor compounds in surface water using solid-phase extraction and gas chromatography-mass

Wenfeng SUN, Ruibao JIA, Baoyu GAO

期刊论文

用于图像融合基于混合全加器和计数器的高效华莱士树型乘法器

Ayoub SADEGHI, Nabiollah SHIRI, Mahmood RAFIEE, Mahsa TAHGHIGH

期刊论文

Simultaneous quantification of several classes of antibiotics in water, sediments, and fish muscles by liquid chromatography–tandem

WEI Yimei,ZHANG Yuan,XU Jian,GUO Changsheng,LI Lei,FAN Wenhong

期刊论文

Numerical analysis of 3-D unsteady flow in a vaneless counter-rotating turbine

ZHAO Qingjun, WANG Huishe, ZHAO Xiaolu, XU Jianzhong

期刊论文

Effect of ligand chain length on hydrophobic charge induction chromatography revealed by molecular dynamics

Lin ZHANG, Yan SUN

期刊论文

analysis of off-flavor/odor compounds in water using liquid-liquid microextraction coupled with gas chromatography—positive

Jian LU,Paul S. WILLS,P. CHRIS WILSON

期刊论文

基于量子点元胞自动机的低能耗、高速度和高效面积时序电路：T型锁存器和计数器研究

Mohammad GHOLAMI1,Zaman AMIRZADEH2

期刊论文